Anwendung von Chlordioxid zur Beseitigung von Legionellen
Zur Zeit läuft eine Untersuchung zur Bestimmung der Dosierung von TwinOxide-Chlordioxidlösungen, um die Legionellenkonzentrationen um ca. 99,999% zu senken. Darüber werde ich später berichten.
Bekanntlich werden Chlordioxid-Lösungen auch aus zwei pulverförmigen Stoffen und Wasser hergestellt.
Im folgende sind die Ergebnisse der Untersuchungen bei Siemens dargestellt, über die in folgender Quelle berichtet wird:
http://www.water.siemens.com/SiteCollectionDocuments/Product_Lines/Wallace_and_Tiernan_Products/Brochures/WT.085.272.017.IE.AN.0409.pdf
Cooling Systems - The ACoP, L8 guidelines state that chlorine
dioxide is effective for the control of Legionella when a
residual
of 0.5 mg/L – 1.0
mg/L is
maintained in the return water. The
effective concentration should be present for at least four out of
every 24 hours when chlorine dioxide is applied intermittently.
Under these guidelines, routine monitoring for the presence of
Legionella is required by an accredited laboratory. If the
aerobic
count cfu/ml at 30°C (minimum 48 hours incubation) is 10,000
or less and the Legionella bacteria cfu/L is 100 or less, the
system is considered under control. If
the Legionella levels are
higher than 100 cfu/L then appropriate action is required.
Hot and
Cold Water Systems – The AcoP states that chlorine dioxide at levels of 0.5 mg/L can, if properly managed, be effective against
planktonic and sessile Legionella in hot water system.
Feed Requirements
For control of bacterial slime and algae
in industrial recirculating
and one-pass cooling systems, the required
dosages will
vary depending on the exact application
and the degree of
contamination present. The required chlorine dioxide residual
concentrations
range between 0.1 and 5.0 mg/L.
Chlorine dioxide may be applied either continuously
or intermittently.
The typical chlorine dioxide residual
concentration range is
0.1 - 1.0 mg/L for continuous doses, and
0.1 - 5.0 mg/L for
intermittent doses.
The minimum acceptable residual
concentration of chlorine
dioxide is 0.1 mg/L for a minimum
one-minute contact time.
Relative Effectiveness of Treatment
Alternatives
In general, the following comparison, in
decreasing order of effectiveness, holds true for control and removal of
bacteria by biocides present under the conditions described:
Bulk Water Bacteria: Biocide efficacy is dependent on the
organism. For Legionella at neutral pH:
O3 >
ClO2 ≥ HOCl ≥ HOBr
Bacterial Biofilms:
ClO2 >>
HOCl ≥ HOBr > O3 > non-oxidizing
Algae:
ClO2 >
certain non-oxidizing > HOCl > O3 > HOBr
Amoebic Cysts and
Protozoa:
O3 > ClO2 >> HOCl > HOBr
( Dr.W. Storch-2013-09-30)
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